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Volume 1, Issue 1 (7-2003)
Abstract

Core samples from the sediments of the Dee Estuary were collect-ed from the chosen sites to study the distribution of pesticides in the sediments. The organic compounds were extracted by a microwave sample preparation system from 56 sediment samples and gas chromatography. Mass spectrometry (GC-MS) was employed for the organic compound analysis. Distribution of n-alkanes in the analysed sediments and calculation of their carbon preference index indicate a continental source for the organic compounds in all samples. Different search strategies were applied to find pesticides in the sediments. Maneb was the only pesticide found in the samples. The distribution of Maneb showed a zigzag pattern with depth in all the four studied areas in the Dee estuary, corresponding to the pattern of distribution of total organics. The highest concentration level of Maneb was 16.33 ng/g of sediment at a depth of 14 cm. The distribution of Maneb with depth is attributed to the seasonal application and release to the environment
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Volume 17, Issue 1 (3-2023)
Abstract

Waste management is a cornerstone of societal needs. The volume and composition of waste dictate the available disposal options, with landfill being a primary method. The selection of landfill sites is critically dependent on site characteristics and requires thorough and ongoing evaluation, particularly in the areas of water and soil contamination. This study started with geoelectrical and geochemical investigations in the vicinity of the landfill in the city of Damavand. It included 24 geoelectric soundings using the Schlumberger array, organized into 4 profiles covering three intervals. In parallel, three water samples, five soil samples and one leachate sample from two intervals were collected for laboratory analysis. Analyses revealed soil contamination at the waste accumulation site to a depth of two meters with a southerly extent. In particular, a cementitious layer prevents leachate from penetrating deeper into the soil. This, together with a very deep groundwater table, ensures that groundwater contamination is currently and in the foreseeable future prevented. Additional factors such as the depth of the groundwater table, the thickness of the unsaturated zone, the short life of the landfill, reduced rainfall and increased evaporation limit the volume of leachate. The pH of the leachate tends to be alkaline during dry periods and acidic during wet periods. Currently, parameters such as EC, TDS and various ionic and metallic concentrations remain within acceptable limits, ensuring minimal environmental impact.


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