Showing 1 results for Acetate Ion. Based on This Calculation
Volume 18, Issue 58 (8-2004)
Abstract
The complex [Fe3O(AcO)6(H2O)3]+ was prepared by treating 1, 3, 5-trimethy l-2, 4, 6-trioxane with FeCl3. 6H2O in the presence of sodium metal. The structure of this complex was calculated by abinitio method as a Hexagonal skeleton with bridging - acetate ion. Based on this calculation D3h symmetry for the central Fe3O unit, and C2v symmetry for trans- Fe O'O"O4 - units chelated on iron ions around the three centred nuclei, are proposed. Combination vibration of these two units resulted in explanation and charactrization of IR spectrum of this compound.
